Entropy driven chain effects on ligation chemistry† †Electronic supplementary information (ESI) available: Synthetic details, applied MHKS parameters, SEC chromatograms of all samples, (HT) NMR data, experimental debonding values, SANS measurements, computational data (energy contributions and geometries in the form of Gaussian archive entries). See DOI: 10.1039/c4sc02908a Click here for additional data file.

Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin† †Electronic supplementary information (ESI) available: General procedures, synthetic details, NMR spectra, EPR spectra, IR spectra, electronic absorption and emission spectra, voltammetric data, X-ray crystallographic data, computational details and optimised geometries. CCDC 1446511, 1446512 and 1507634. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c6sc02912d Click here for additional data file. Click here for additional data file.

EaStCHEM School of Chemistry, The Unive David Brewster Road, Edinburgh, EH9 3FJ, [email protected] LPCNO, INSA, Université de Toulouse, 13 cedex 4, France Centre for Radiochemisty Research, Sch Manchester, Oxford Road, Manchester, M13 WestCHEM School of Chemistry, University † Electronic supplementary information synthetic details, NMR spectra, EPR spe and emission spectra, voltammetric computati...

Racemic hemiacetals as oxygen-centered pronucleophiles triggering cascade 1,4-addition/Michael reaction through dynamic kinetic resolution under iminium catalysis. Development and mechanistic insights† †Electronic supplementary information (ESI) available: Detailed experimental procedures and characterization of all new compounds, including copies of NMR spectra and HPLC chromatograms traces, computational details and Cartesian coordinates of all stationary points. CCDC 1525188 (4l), 1525189 (6a) and 1525190 (9a). For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc00009j Click here for additional data file. Click here for additional data file.

Department of Organic Chemistry II, Unive P.O. Box 644, 48080 Bilbao, Spain Departamento de Śıntesis y Estructura de Bi y Catálisis Homogénea (ISQCH), Universida Servicio de Resonancia Magnética Nuclear, C (CEQMA), Universidad de Zaragoza, CSIC, † Electronic supplementary information procedures and characterization of all NMR spectra and HPLC chromatogram Cartesian coordinates of all stationary...

Self-assembling α,γ-cyclic peptides that generate cavities with tunable properties† †Electronic supplementary information (ESI) available: Synthetic experimental details, DFT calculation details, additional figures (relevant NMR data) and schemes (synthetic schemes for peptide and amino acid preparation). CCDC 1400134. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc03187g Click here for additional data file. Click here for additional data file.

A nitrogen-base catalyzed generation of organotin(ii) hydride from an organotin trihydride under reductive dihydrogen elimination† †Electronic supplementary information (ESI) available: Detailed information concerning the general synthetic procedures, NMR spectroscopy and crystallographic details. Detailed explanations on the kinetic measurements and selected 1D NMR spectra as well as details on the computational considerations. CCDC 1061347–1061349. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01561h Click here for additional data file. Click here for additional data file.

Institut für Anorganische Chemie, Auf Germany. E-mail: lars.wesemann@uni-tueb School of Chemistry, Monash University, PO Institut für Organische Chemie, Auf der Mo † Electronic supplementary information concerning the general synthetic p crystallographic details. Detailed explanat selected 1D NMR spectra as well considerations. CCDC 1061347–1061349. CIF or other electronic format see DOI: 10 Ci...

Counterion influence on the N–I–N halogen bond† †Electronic supplementary information (ESI) available: Experimental details of synthesis, compound characterisation, IPE NMR measurements, computational and crystallographic procedures, and crystal data for 1-Ag/I to 7-Ag/I, and 12-Ag. CCDC 1045981–1045995. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01053e Click here for additional data file. Click here for additional data file.

Department of Chemistry and Molecular Bio Gothenburg, Sweden. E-mail: [email protected] University of Jyvaskyla, Department of Chem FI-40014 University of Jyvaskyla, Finland Department of Chemistry and RECETOX, Brno, Czech Republic The Swedish NMR Centre, Medicinaregatan Department of Applied Chemistry, Faculty o Prilaz baruna Filipovića 28a, HR-10000 Zag † Electronic supplementary information synthe...